| Rt Hon Henry Sidney, Viscount Sydney | 1691 | 1702 |
| Robert Banks Jenkinson, Baron Hawkesbury | 1806 | 1827 |
| Rt Hon Sir Arthur Wellesley, Marquess of Douro | 1829 | 1852 |
| Rt Hon Sir Granville George Leveson-Gower, Earl Granville | 1865 | 1865 |
| Rt Hon William Henry Smith | 7 May 1891 | 6 October 1891 |
| Sir Thomas Brassey | 1908 | 1913 |
| Rt Hon William Lygon, Earl Beauchamp | 1913 | 1934 |
| Rt Hon Sir Rufus Daniel Isaacs, Marquess of Reading | 1934 | 1935 |
| Sir Michael Cecil Boyce, Baron Boyce | 10 December 2004 | 6 November 2022 |