| George Dodington |
1707 | 1708 |
| Augustus John Hervey |
1766 | 1767 |
| George Macartney |
1768 | 1772 |
| Rt Hon Sylvester Douglas |
1794 | 1795 |
| Robert Stewart, Viscount Castlereagh |
1798 | 1801 |
| Charles Abbot |
1801 | 1802 |
| Rt Hon William Wickham |
February 1802 | January 1804 |
| Sir Evan Nepean, bt |
January 1804 | September 1804 |
| Rt Hon Arthur Wellesley |
1807 | 1808 |
| Rt Hon William Wellesley-Pole |
1809 | 1812 |
| Rt Hon Robert Saunders-Dundas |
April 1809 | October 1809 |
| Robert Peel |
May 1812 | 1818 |
| Rt Hon Charles Grant |
August 1819 | 1823 |
| Rt Hon Henry Goulburn |
December 1821 | April 1827 |
| Rt Hon William Lamb |
1827 | 1828 |
| Rt Hon Francis Egerton |
21 June 1828 | 30 July 1830 |
| Rt Hon Henry Hardinge |
30 July 1830 | 15 November 1830 |
| Rt Hon Edward George Geoffrey Smith Stanley |
29 November 1830 | 29 March 1833 |
| Rt Hon Sir John Cam Hobhouse, bt |
29 March 1833 | May 1833 |
| Rt Hon Edward John Littleton |
May 1833 | 14 November 1834 |
| Rt Hon Henry Hardinge |
16 December 1834 | 8 April 1835 |
| George William Frederick Howard, Viscount Morpeth |
22 April 1835 | 30 August 1841 |
| Rt Hon Edward Granville Eliot, Baron Eliot |
6 September 1841 | 1 February 1845 |
| Rt Hon Sir Thomas Francis Fremantle, bt |
1 February 1845 | 14 February 1846 |
| Henry Pelham Clinton, Earl of Lincoln |
14 February 1846 | June 1846 |
| Rt Hon Henry Labouchere |
6 July 1846 | 22 July 1847 |
| Rt Hon Sir William Meredyth Somerville, bt |
22 July 1847 | 21 February 1852 |
| Rt Hon Richard Southwell Bourke, Baron Naas |
1 March 1852 | 17 December 1852 |
| Sir John Young, bt |
6 January 1853 | 30 January 1855 |
| Edward Horsman |
1 March 1855 | 27 May 1857 |
| Rt Hon Henry Arthur Herbert |
27 May 1857 | 21 February 1858 |
| Rt Hon Richard Southwell Bourke, Baron Naas |
4 March 1858 | 11 June 1859 |
| Rt Hon Edward Cardwell |
24 June 1859 | 29 July 1861 |
| Rt Hon Sir Robert Peel, bt |
29 July 1861 | 7 December 1865 |
| Rt Hon Chichester Samuel Parkinson-Fortescue |
7 December 1865 | 26 June 1866 |
| Rt Hon Richard Southwell Bourke, Baron Naas |
10 July 1866 | 29 September 1868 |
| Rt Hon John Wilson Patten |
29 September 1868 | 1 December 1868 |
| Rt Hon Chichester Samuel Parkinson-Fortescue |
16 December 1868 | 12 January 1871 |
| Rt Hon Spencer Compton Cavendish, Marquess of Hartington |
12 January 1871 | 17 February 1874 |
| Rt Hon Sir Michael Edward Hicks-Beach, bt |
27 February 1874 | 15 February 1878 |
| Rt Hon James Lowther |
15 February 1878 | 21 April 1880 |
| Rt Hon William Edward Forster |
30 April 1880 | 2 May 1882 |
| Frederick Charles Cavendish |
6 May 1882 | 6 May 1882 |
| George Otto Trevelyan |
9 May 1882 | 23 October 1884 |
| Sir Henry Campbell-Bannerman |
23 October 1884 | 9 June 1885 |
| Rt Hon Sir William Hart Dyke, bt |
25 June 1885 | 23 January 1886 |
| Rt Hon William Henry Smith |
23 January 1886 | 28 January 1886 |
| Rt Hon John Morley |
6 February 1886 | 20 July 1886 |
| Rt Hon Sir Michael Edward Hicks-Beach, bt |
5 August 1886 | 7 March 1887 |
| Rt Hon Arthur James Balfour |
7 March 1887 | 9 November 1891 |
| Rt Hon William Lawies Jackson |
9 November 1891 | 11 August 1892 |
| Rt Hon John Morley |
22 August 1892 | 21 June 1895 |
| Rt Hon Gerald William Balfour |
2 July 1895 | 1900 |
| Rt Hon George Wyndham |
9 November 1900 | 12 March 1905 |
| Rt Hon Walter Hume Long |
12 March 1905 | 4 December 1905 |
| Rt Hon James Bryce |
10 December 1905 | 23 January 1907 |
| Rt Hon Prof Augustine Birrell |
23 January 1907 | 3 May 1916 |
| Richard Harold St Maur |
1916 | |
| Rt Hon Sir Henry Edward Duke |
31 July 1916 | 6 May 1918 |
| Edward Shortt |
5 May 1918 | 10 January 1919 |
| Rt Hon James Ian Macpherson |
10 January 1919 | 2 April 1920 |
| Sir Thomas Hamar Greenwood, bt |
2 April 1920 | 19 October 1922 |