| Charles Watkin Williams Wynn | 1806 | 1807 |
| George Robert Dawson | 1822 | 1827 |
| Sir George Clerk, bt | August 1830 | November 1830 |
| Fox Maule | 1835 | 1841 |
| Edward Adolphus Seymour, Baron Seymour | June 1841 | August 1841 |
| Sir William Meredyth Somerville, bt | 1846 | 1847 |
| Rt Hon Edward Pleydell-Bouverie | 9 July 1850 | 21 February 1852 |
| William Francis Cowper-Temple | 1855 | 1855 |
| William Nathaniel Massey | August 1855 | March 1858 |
| Henry Austin Bruce | 1862 | 1864 |
| Thomas George Baring | 1864 | 1866 |
| Sir James Fergusson, bt | August 1867 | 1868 |
| Sir Michael Edward Hicks-Beach, bt | 1868 | |
| George John Shaw-Lefevre | January 1871 | March 1871 |
| Sir Henry Hartley Fowler | 1884 | 1885 |
| Ellis Jones Ellis-Griffith | 1912 | 1915 |