| Rt Hon Michael Andrew Gove | 15 September 2021 | 6 July 2022 |
| Rt Hon Dr Gregory David Clark | 7 July 2022 | 6 September 2022 |
| Rt Hon Simon Richard Clarke | 6 September 2022 | |
| Rt Hon Michael Andrew Gove | 25 October 2022 | 5 July 2024 |
| Rt Hon Angela Rayner | 5 July 2024 | 5 September 2025 |